If the concentration of KMnO4 was 0.0235 M, calculate the number of moles of MnO4- ions that completely reacted with the H2C2O4

Answer:

Hence, 15.99 g of solid Aluminum Sulfate should be added in 250 mL of Volumetric flask.

Explanation:

To make 0.187 M of Aluminum Sulfate solution in a 250 mL (0.250 L) Volumetric flask  

The molar mass of Aluminum Sulfate = 342.15 g/mol  

Using the molarity formula:-  

Molarity = Number of moles/Volume of solution in a liter  

Number of moles = Given weight/ molar mass  

Molarity = (Given weight/ molar mass)/Volume of solution in liter  

0.187 M = (Given weight/342.15 g/mol)/0.250 L  

Given weight = 15.99 g  

The question is incomplete. The complete question is :

An analytical chemist is titrating 148.9 mL of a 1.100 M solution of benzoic acid [tex]$HC_6H_5CO_2$[/tex]  with a 0.3600 M solution of KOH. The [tex]pK_a[/tex]  of benzoic acid is 4.20. Calculate the pH of the acid solution after the chemist has added 232.0 mL of the KOH solution to it. Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of KOH solution added.

Solution :

Number of moles of [tex]$C_6H_5OCOOH$[/tex] [tex]$=148.9 \ mL \times \frac{L}{1000\ mL} \times \frac{1.100 \ mol}{L}$[/tex]

                                                         = 0.16379 mol

Number of moles of NaOH added [tex]$=232.0 \ mL \times \frac{L}{1000\ mL} \times \frac{0.3600 \ mol}{L}$[/tex]

                                                         = 0.08352 mol

ICE table :

                     [tex]C_6H_5OCOOH \ \ \ + \ \ \ OH^- \ \ \ \rightarrow \ \ C_6H_5OCOO^- \ \ \ \ + \ \ H_2O[/tex]

I (mol)              0.16379                 0.08352              0

C (mol)           -0.08352              -0.08352            +0.08352

E (mol)            0.08027                    0                    0.08352

Total volume = (148.9 + 232) mL

                      = 380.9 mL

                     = 0.3809 L

Concentration of [tex]$C_6H_5OCOOH, [C_6H_5OCOOH]$[/tex] [tex]$=\frac{0.08027 \ mol}{0.3809 \ L}$[/tex]

                                                                               = 0.211 M

Concentration of [tex]$C_6H_5OCOO^- , [C_6H_5OCOO^-] =\frac{0.08352 \ mol}{0.3809 \ L}[/tex]

                                                                              = 0.219 M

[tex]pK_a[/tex] of [tex]C_6H_5OCOOH = 4.20[/tex]

According to Henderson equation,

[tex]$pH = pK_a + \log \frac{[C_6H_5OCOO^-]}{[C_6H_5OCOOH]}[/tex]

     [tex]$=4.20 + \log \frac{0.219}{0.211}$[/tex]

     = 4.22

Therefore, the pH of the acid solution is 4.22

Answer:

It is known that 1 mol of a molecule contains 6.023×1023 6.023 × 10 23 number of molecules. So, 0.25 moles of CO2 C O 2.

The correct option for the given question about Mole Concept is Na / 2 atom of oxygen.

In 1 mole number of molecules of CO₂ = Na (Avagadro Number)

In 0.25 mole number of molecules of CO₂ = 0.25 × Na molecules

In 1 molecule number of oxygen atom = 2 atom

In 0.25 × Na molecules number of oxygen atom = 2 × 0.25 × Na atom

In 0.25 × Na molecules number of oxygen atom = 0.5 × Na atom

So in 0.25 mole of CO₂ number of oxygen atom = Na / 2 atom

Thus we can conclude that in 0.25 mole of CO₂ number of oxygen atom will be Na / 2, where Na is Avagadro Number.

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Answer:

In Haloarenes the C atom to which the X group is attached is SP2 hybridized thus it is become difficult to replace it by the Nucleophile. Since arenes and Vinyl halides are electron rich molecules due to presenceof n bonds, they repel Nucleophile attacking them.

Question:-

Why it is difficult for haloarenes to undergo nucleoplhilic subsituⁿ reaction?

Answer:-

Haloarenes are less reactive towards the nucleoplhilic substitution rxⁿ . This is due to following reasons :-

[tex]\red{\bigstar}\underline{\textsf{ Reason 1 :- Partial double bond character .}}[/tex]

Halogen atom has one lone pair, and due to presence of π - σ - lp , resonance is established in the compound ( see attachment) . Due to resonance there is a partial double bond character in the carbon halogen bond , so it is difficult to break a double bond than a single bond.

[tex]\rule{200}2[/tex]

[tex]\red{\bigstar}\underline{\textsf{ Reason 2 :- $\pi$ cloud .}}[/tex]

When a nucleoplhile comes to attack , it is repelled by the π-cloud of the benzene ring.

[tex]\rule{200}2[/tex]

[tex]\red{\bigstar}\underline{\textsf{ Reason 3 :- Phenyl cation .}}[/tex]

If somehow the halogen atoms leaves the benzene ring ,being more electronegative than carbon , it takes away the electron , thus a positive charge is left on benzene ring and the phenyl cation so formed is very unstable .

[tex]\rule{200}2[/tex]

Explanation:

The given chemical reaction is:

[tex]2 N_2 (g) + O_2(g) -> 2 N_20 (g) delta Hrxn= +163.2 kJ[/tex]

When two moles of nitrogen reacts with oxygen, it requires 163.2kJ of energy.

When 5.00 mol of nitrogen requires how much energy?

[tex]5.00 mol x \frac{163.2 kJ }{2 mol} \\=408 kJ[/tex]

Hence, the answer is 408 kJ of heat energy is required.

Answer:

21.3 g. Option B

Explanation:

The reaction is:

4HF(g) + SiO₂(s) → SiF₄(g) + 2H₂O(g)

We analysed it and it is correctly balanced.

4 moles of hydrogen fluoride react to 1 mol of silicon dioxide in order to produce 1 mol of silicon fluoride and 2 moles of water vapor.

We determine molar mass of each reactant:

HF → 1.01 g/mol + 19 g/mol = 20.01 g/mol

SiO₂ → 16 g/mol . 2 + 28.09 g/mol = 60.09 g/mol

We convert mass to moles: 16 g . 1 mol /60.09g = 0.266 moles of glass

Ratio is 1:4. 1 mol of glass react to 4 moles of HF

Our 0.266 moles may react to (0.266 . 4) / 1 = 1.07 moles of gas

We convert moles to mass: 1.07 mol . 20.01 g/mol = 21.3 g

Answer:

The answer is "Option b".

Explanation:

H2 does have bond energy of 1, while Be2 has a covalent bond of zero. Be2 has eight electrons, each of which dwells in a distinct orbital. As just a result, four of them are linked molecular orbitals and two are antibonding molecular orbitals, respectively. As just a result, this molecule is unstable. This chemical orbital, with a bond order of 1, has just two electrons. As a result, it is a very solid substance. H2's bond length is higher than Be2's. Since it only has one electron, H2 is more stable than that of other compounds.

Answer:

1) HNO3/H2SO4, 2) CH3CH2CH2Cl/AlCl3

Explanation:

Benzene is a stable aromatic compound hence it undergoes substitution rather than addition reaction.

When benzene undergoes substitution reaction, the substituent introduced into the ring determines the position of the incoming electrophile.

If I want to synthesize m-nitropropylbenzene, I will first carry out the nitration of benzene using HNO3/H2SO4 since the -nitro group is a meta director. This is now followed by Friedel Craft's alkykation using CH3CH2CH2Cl/AlCl3.

Answer:

HCl contain a polar covalent bond because H is more electropositive than Cl and Cl is more electronegative than H, resulting in a dipole moment

Answer:

495 J

Explanation:

When the hot pot was set on the counter to cool, heat energy was lost from the pot. Note that according to the first law of thermodynamics, heat is neither created nor destroyed.

This implies that, the heat energy lost from the pot must be gained by the surrounding air. Therefore, if 495 J of energy is lost from the pot, then 495 J of energy is gained by the surrounding air.

Answer:

Explanation:

From the given information:

The surface area of the can = (30 × 20 × 2) +(20× 15 × 2) +(30 × 15 × 2)

= 1200 + 600 + 900

= 2700 cm²

Since 1 inch² = 0.155 inch²

The surface area in inches² = 2700 × 0.155 inch²

= 418.5 inches²

The total force can be determined by using the expression:

Force = Pressure ×Area

Force = 14.7 psi ×  418.5 inches²

Force = 6151.95 lbs

Yes, the gasoline can will be able to withstand the force.

Answer:

The amount of CH3OH present in the mixture would decrease

Explanation:

According to Le Cha-telier's principle, when a reaction is in equilibrium and one of the constraints that influence the rate of reactions is applied, the equilibrium would shift so as to neutralize the effects of the constraint.

In this case, looking at the equation of the reaction:

2H2 + CO <------> CH3OH + heat

the total number of moles on the reactant's (left hand) side is 3 (2+1) while on the product's (right hand) side, it is 1. If the pressure on the system is increased, more CH3OH (and less of H2 and CO) will be produced because its side has the lower number of moles out of the two sides.

If the pressure on the system is otherwise lowered, more of H2 and CO would be produced while the amount of CH3OH present would gradually decrease.

The solid that require the greatest energy input to melt by mass is the option;

Covalent network

Reason for the above answer is as follows;

The elementary particles of a solid are held together by bonds that require

an input of energy to unlock, and once broken, the particles are then able

to change location within their containing vessels with less restrictions

Types of bonds

a) Soluble in water b) Low melting point, b) Conduct electricity

a) High melting point temperature b) Non conductive of electricity c) Not soluble in water

a) High melting point temperature b) The liquid state and solution

conducts electricity c) Soluble in water

a) Low melting point b) Normally in the gaseous or liquid state b) Not water soluble

Therefore, the covalent network, and the solids ionic compounds require the most energy to melt, however, the strength of the ionic bond in an ionic compound is a factor the charges present and the sizes of the atom, while

the covalent network solid, are combined to form essentially as a single

molecule and therefore require the greatest heat energy input break the bonds of the molecule down in order to melt

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Explanation:

here's the answer to the question

Answer:

[tex]\boxed {\boxed {\sf D. \ 0.25 \ M}}[/tex]

Explanation:

Molarity is a measure of concentration in moles per liter.

[tex]molarity= \frac{moles \ of \ solute}{ liters \ of \ solution}[/tex]

The solution contains 0.75 moles of sodium chloride and has a volume of 3.0 liters.

Substitute these values into the formula.

[tex]molarity= \frac{ 0.75 \ mol \ NaCl}{3.0 \ L}[/tex]

[tex]molarity= 0.25 \ mol \ NaCl/L[/tex]

Molarity has the molar (M) as its unit. 1 molar is equal to 1 mole per liter.

[tex]molarity= 0.25 \ M \[/tex]

The molarity of the solution is 0.25 Molar and Choice D is correct.

Answer:

requiring immediate action or attention.

word similar to urgent: Acute

Answer:

a) N2

b) They all have the same average kinetic energy.

Explanation:

At a given temperature, the speed of a gas molecule depends on its relative molecular mass. The heavier the gas, the lesser its average velocity at a given temperature. On that basis, N2 molecules are the fastest moving gas molecules.

At a particular temperature, all gases have the same average kinetic energy.

Answer:

In three mocelus 0.0001 gram.

Answer:

25.5mL of 0.100M NaOH are needed to reach buffer capacity.

Explanation:

The buffer capacity is reached when the ratio between moles of conjugate base (Sodium acetate) and moles of weak acid (Acetic acid) is 10:

Moles sodium acetate / Moles Acetic acid = 10

The reaction of acetic acid, HA, with NaOH, to produce sodium acetate, NaA is:

HA + NaOH → H2O + NaA

That means the moles of NaOH added = Moles of HA that are being subtracted and moles of NaA that are been produced.

The initial moles of each species is:

Acetic acid:

23.34mL = 0.02334L * (0.147mol / L) = 0.00343 moles Acetic Acid

Sodium Acetate:

33.66mL = 0.03366L * (0.185mol / L) = 0.00623 moles Sodium Acetate

We can write the moles of each species when NaOH is added as:

Moles sodium acetate / Moles Acetic acid = 10

0.00623 moles + X / 0.00343 moles - X = 10

Where X are moles of NaOH added

Solving for X:

0.00623 moles + X = 0.0343 moles - 10X

11X = 0.0281

X = 0.00255 moles of NaOH are needed

In Liters:

0.0255mol NaOH * (1L / 0.100mol) = 0.0255L of 0.100M NaOH are needed =

Answer:

[tex]x=54g[/tex]

Explanation:

From the question we are told that:

Content of Sterling silver:

Let x be sterling silver

Silver [tex]S=0.9x[/tex]

Copper [tex]C=0.1x[/tex]

Total  silver available [tex]T=48.3[/tex]

Generally the equation for Total amount to be made is mathematically given by

[tex]T=\frac{x*90}{100}[/tex]

[tex]x=\frac{48.3*100}{90}[/tex]

[tex]x=54g[/tex]

Stoichiometry refers to the relationship between the moles of reactants and products.

This question must be solved using both stoichiometry and the gas laws

The reaction equation is;

2 Al(s) + 6 HCl(aq) --------> 2 AICI3, (aq) + 3 H2(g)

Number of moles of Al = 3g/27g/mol = 0.11 moles

According to the reaction equation;

2 moles of Al yields 3 moles of H2

0.11 moles of Al yields 0.11 * 3/2 = 0.165 moles

From the ideal gas equation;

PV=nRT

P = ?

n= 0.165 moles

V = 0.85 L

T = 297 K

R = 0.082 atmLK-1mol-1

P= nRT/V

P = 0.165 * 0.082 * 297/0.85

P= 4.73 atm

P1 = 4.73 atm

T1 = 297 K

V1 = 0.85 L

P2 = 1 atm

T2 =273 K

V2 =?

P1V1/T1 = P2V2/T2

P1V1T2 = P2V2T1

V2 = P1V1T2/P2T1

V2 =  4.73 * 0.85 * 273/1 * 297

V2 = 3.69 L

P1 = 760 mmHg

T1 = 273 K

V1 = 3.69

P2 = 438 mm Hg

T2 = 284.2 K

V2 =?

P1V1/T1 = P2V2/T2

P1V1T2 = P2V2T1

V2 = P1V1T2/P2T1

V2 = 760 * 3.69 * 284.2/438 *273

V2 = 797010.48/119574

V2= 6.67 L

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Solution : An oxidation reduction (redox) reaction is a type of chemical reaction that involves a transfer of electrons between tow species an oxidaion reductin reaction is any chemical reaction in which the oxidation number of a molecule atom or ion changes by gaining or losing an electron

Answer:

8.3 g

Explanation:

Step 1: Write the balanced equation

H₃PO₄ + 3 NH₃ ⇒ (NH₄)₃PO₄

Step 2: Calculate the moles corresponding to 5.5 g of H₃PO₄

The molar mass of H₃PO₄ is 97.99 g/mol.

5.5 g × 1 mol/97.99 g = 0.056 mol

Step 3: Calculate the moles of (NH₄)₃PO₄ produced

The molar ratio of H₃PO₄ to (NH₄)₃PO₄is 1:1. The moles of (NH₄)₃PO₄ produced are 1/1 × 0.056 mol = 0.056 mol.

Step 4: Calculate the mass corresponding to 0.056 moles of (NH₄)₃PO₄

The molar mass of (NH₄)₃PO₄ is 149.09 g/mol.

0.056 mol × 149.09 g/mol = 8.3 g

Answer:

Aqueous workup.

Explanation:

The reaction of hexyl magnesium bromide with acetone yields a tertiary alcohol. There is an organic phase and an aqueous phase.

Aqueous workup is the process of recovering the pure tertiary alcohol from the organic phase of the system.

Hence, in order to complete the reaction of hexyl magnesium bromide with acetone, aqueous workup is required.

Answer:

The two carbon atoms share a total of six electrons with each other.

Explanation:

Looking at the structure of the molecule H-C≡C-H as shown in the question, we will notice that there exists a triple bond between the two carbon atoms.

Each bond between the two carbon atoms represents two electrons shared. Since there are three bonds between the two carbon atoms, then a total of six electrons were shared between the two carbon atoms hence the answer chosen above.

The reaction used to produce sugar in plants is Photosynthesis,

6CO₂ + 6H₂O + heat ⇆ C₆H₁₂O₆ + 6O₂↑

we can see that this reaction is endothermic, it absorbs heat to occur

If we were to add more heat or increase the temperature, the left side of the equilibrium will be able to react much more, which would produce more glucose (aka sugar)

Hence increasing the temperature will shift the equilibrium to the right or towards the Products

Answer:

Explanation:

The reaction that occurs in plants to create sugar can be represented by the following equation:

6 CO2 + 6 H2O ↔ C6H12O6 + 6 O2

It is called photosynthesis because the reaction requires light energy for the plant.  The reaction is controlled by enzyme within the plant. An increase in temperature will increase the collisions between enzyme and reactants; shifting the equilibrium towards the products, sugar and oxygen.

Activation energy is the energy needed to begin breaking the bonds of reactants. Hence, option A is correct.

Activation energy is defined as the minimum amount of energy necessary to initiate a chemical reaction.

Hence, activation energy is the energy needed to begin breaking the bonds of reactants.

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Answer:

The lewis structure for NO₃⁻ is shown in the attachment below

For the central nitrogen atom:

The number of lone pairs = 0

The number of single bonds = 2  

The number of double bonds= 1

Explanation:

The lewis structure for NO₃⁻ is shown in the attachment below.

From the Lewis structure

For the central nitrogen atom:

The number of lone pairs = 0

The number of single bonds = 2  

The number of double bonds= 1

Answer:

-376 kJ

Explanation:

The first step equation:

[tex]\mathsf{N_{2(g)} + 3H_2{(g)} \to 2NH_3{(g)} \ \ \ \Delta H = -92\ kJ}[/tex]    ---- (1)

The second step equation:

[tex]\mathsf{NH_{3(g)} + 2O_2{(g)} \to HNO_3{(g)} +H_2O_{(g)} \ \ \ \Delta H = -330\ kJ}[/tex]      ---- (2)

To determine the enthalpy of formation for 1 mole of HNO₃ (nitric acid), we have the following.

From the above equations; let multiply equation (1) by 1 and equation (2) by 2.

[tex]\mathsf{N_{2(g)} + 3H_2{(g)} \to 2NH_3{(g)} \ \ \ \Delta H = -92\ kJ}[/tex]     ---- (3)

[tex]\mathsf{2NH_{3(g)} + 4O_2{(g)} \to 2HNO_3{(g)} +2H_2O_{(g)} \ \ \ \Delta H = 2(-330)\ kJ}[/tex]      ----- (4)

adding the above two equations, we have:

[tex]\mathsf{N_{2(g)} + 3H_2{(g)}+ 2NH_{3(g)} + 4O_{2(g)} \to 2HNO_{3(g)} + 2NH_3{(g)} +2H_2O_{(g)} \ \ \ \Delta H = (-660 \ kJ -92\ kJ)}[/tex][tex]\mathsf{N_{2(g)} + 3H_2{(g)} + 4O_{2(g)} \to 2HNO_{3(g)} +2H_2O_{(g)} \ \ \ \Delta H = (-752 \ kJ)}[/tex]

Now, from the recent equation, we have:

2 moles of nitric acid = -752 kJ

∴

1 mole of nitric acid will be: = (1 mole × (-752 kJ)) ÷ 2 moles

1 mole of nitric acid will be: = -376 kJ